I always use Chevron Techron fuel additive at least twice per year, and also 2 tankfulls back to back (2 bottles)
This stuff enjoys the best reputation of any fuel additive for cleaning carbon deposits from valves, and pistons. Here is a copy of a few Q&A's from the Chevron web site on why and how it works.
I have never had a problem with pinging, and stick to this preventive maintenance schedule.
Pilot
The principal difference between TechronŽ and TechronŽ Concentrate is additive concentration and rate of deposit clean-up. At the concentration present in Chevron gasolines, TechronŽ over many tankfuls will help clean up deposits on intake valves without contributing to combustion chamber deposits. So, over time, Chevron gasolines with TechronŽ are able to reduce or eliminate deposit-related hesitation and stumbling during acceleration caused by deposits. A bottle of TechronŽ Concentrate, when added to gasoline according to the label instructions, results in an additive concentration roughly 10 times stronger than the dose in our gasolines. This mega-dose of TechronŽ provides a much quicker clean up of intake valve deposits left by lower quality gasolines. In addition, the high concentration of TechronŽ reduces combustion chamber deposits, which can help reduce or eliminate deposit-related engine knock and run-on.
Do I need to use TechronŽ Concentrate if I buy only Chevron gasoline?
If you're a loyal buyer of exclusively Chevron gasolines, your car very likely is delivering its best possible performance and operating at its lowest possible emissions. A bottle of TechronŽ Concentrate, therefore, is not likely to provide any benefits. However, if you sometimes purchase a lower quality gasoline, you should try TechronŽ Concentrate to quickly restore performance lost due to deposit accumulation.
Is TechronŽ just a more diluted version of TechronŽ Concentrate?
Not precisely. While both are polyether amines of very similar structure, each is optimized for its particular application. TechronŽ cleans engines and keeps them clean through regular use of a lower additive dose, while TechronŽ Concentrate provides a quicker clean-up through intermittent use of a higher additive dose.>
http://www.chevron.com/prodserv/fuels/gas_qanda/tech_con.shtml