XP makes it pretty fool proof, since it's really good at detecting all kinds of hardware, most likely you shouldn't have any problems getting on line after to download any missing drivers (if any, unlikely).
One thing you might want to do though is have the computer un-connected from the net. If you're on dial-up modem don't worry about it, but unplug it from the cable modem or DSL router. Reason is, a virgin XP installation is wide open to lots of easy exploits and chances are it'll get infected within minutes.
Install it, configure the firewall, then plug it up and do the Windows Updates first.
http://www.microsoft.com/athome/security/protect/default.aspx